Absence of simulation evidence for critical depletion in slit pores.
نویسندگان
چکیده
Recent Monte Carlo simulation studies of a Lennard-Jones fluid confined to a mesoscopic slit pore have reported evidence of "critical depletion" in the pore local number density near the liquid-vapor critical point. In this Brief Report we demonstrate that the observed depletion effect is in fact a simulation artifact arising from small systematic errors associated with the use of long range corrections for the potential truncation. Owing to the large near-critical compressibility, these errors lead to significant changes in the pore local number density. We suggest ways of avoiding similar problems in future studies of confined fluids.
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ورودعنوان ژورنال:
- Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics
دوره 60 1 شماره
صفحات -
تاریخ انتشار 1999